Degumming
Soybean oil contains over 2% phosphatides.They are precipit- ated by water addition and separated in the degumming process.
Wet gums can be added back to the meal in the DT, or dried to produce lecithin.
Neutralising
These unit operations reduces free fatty acids to below 0.08% and phosphorus to below 3 mg/kg. Iron and copper concentrations are reduced to
below the detection limit. Coloured compounds (chlorophylloids, carotenoids) are not affected significantly, altough chlorophylloids can be reduced
by 30-70% of the original concentration under certain process conditions. The concentration of sulfur compounds is reduced slightly.
Bleaching
The neutralized oil is usually golden yellow, which is not yet suitable for food purposes.It is necessary to bleach the oil so as to remove
the various pigments not removed by neutralization. This is done with adsorbents in the form of bleaching earth or activated charcoal.
Soybean oil is bleached at a maximum temperature of 100°C- 105°C. The bleaching earth must be used in concentrations of 0.3-0.5% of the oil
weight in chemical refining.
Deodorising
For soybean oil in chemical refining we can present some typical operating parameters:
| Temperature : |
230-240°C |
| Pressure: |
2-3 mbar |
| Deo time: |
40-60 min |
| Final FFA : |
0.03-0.05% |
| Trans FA: |
0.5-1% |
| Toco losses: |
25% max |
The improved deodorisation technology has led to a perfect overall refined oil quality:
- Low residual FFA and high oxidative stability
- Light color, bland odor and taste
- Low trans and polymeric triglyceride content
Furthermore we are perfectly in control of the removal of minor components:
- Adjustable process conditions
- Limited thermal/oxidative degradation.
A special Dual Temp® Deodoriser is also available with:
- Low temperature-long time for mild deodorising and moderate stripping and thermolytic/hydrolytic breakdown reactions
- High temperature-short time for stripping and heat bleaching and for controlled removal/retention of valuable minor components
Hydrogenation
Oil quality required for the hydrogenation:
| Free fatty acids: |
< 0.05% |
| Soaps: |
< 25 ppm |
| Phosphorus: |
< 2 ppm |
| Moisture: |
< 0.05% |
| Peroxide value: |
< 0.5 meq/kg |
| p-Anisidine value: |
< 10 |
Interesterification
Interesterification is used to :
- change the overall melting profile (usually to smoothen the solid fat content) or the melting point of the mixture (usually a decrease)
- improve the compatibility of the different triglycerides in the solid state
- improve the plasticity of the resulting solid by changing the (re)crystallisation properties
- combine the properties of mixed oils and fats
Fractionation
Dry fractionation is the simplest and cheapest modification process, as it is not the source of oil losses, any more than it requires
supplementary post-treatment of the finished products.
Especially in today’s fast changing market, fractionation offers some serious advantages over hydrogenation and interesterification.
The very low operating costs as well as the zero oil loss and full reversibility of the process make it most attractive.